Cross-Coupling Reactions of Organosilicon Compounds: New Concepts and Recent Advances.
نویسندگان
چکیده
منابع مشابه
Cross-coupling reactions of organosilicon compounds: new concepts and recent advances.
This review highlights the rapid evolution of the newly-developed class of palladium-catalyzed cross-coupling reactions of organosilicon compounds. A myriad of heteroatom-containing silicon moieties (silyl hydrides, siletanes, silanols, silyl ethers, orthosiliconates, di- and polysiloxanes and pyridylsilanes) undergo mild and stereospecific cross-coupling. The diversity of methods for introduct...
متن کاملPalladium-catalysed cross-coupling of organosilicon reagents.
The palladium catalysed cross-coupling of organosilicon reagents with organo halides and pseudo-halides has developed over the past 30 years into an efficient and attractive carbon-carbon bond forming strategy. Extensive research within this field to expand and diversify on the scope of the organosilicon coupling reaction will continue to promote its use in the synthesis of biologically and pha...
متن کاملRecent advances in noble metal nanocatalysts for Suzuki and Heck cross-coupling reactions.
Since metal nanoparticles have a high surface-to-volume ratio and very active surface atoms, they are very attractive catalysts for a wide variety of organic and inorganic reactions, compared to bulk catalysts. Metal nanoparticles suspended in colloidal solutions and those adsorbed onto bulk supports have been used as catalysts for a wide variety of carbon-carbon bond formation reactions such a...
متن کاملRecent advances in the cross-coupling reactions of organoboron derivatives with organic electrophiles, 1995–1998
The palladium-catalyzed cross-coupling reaction between organoboron compounds and organic halides or triflates provides a powerful and general methodology for the formation of carbon–carbon bonds. Recently, this reaction has been called the Suzuki coupling, Suzuki reaction, or Suzuki–Miyaura coupling, although we never referred to it as such previously. In this review, this name will be used wi...
متن کاملRecent advances in copper-catalyzed asymmetric coupling reactions
Copper-catalyzed (or -mediated) asymmetric coupling reactions have received significant attention over the past few years. Especially the coupling reactions of aryl or alkyl halides with nucleophiles became a very powerful tool for the formation of C-C, C-N, C-O and other carbon-heteroatom bonds as well as for the construction of heteroatom-containing ring systems. This review summarizes the re...
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ژورنال
عنوان ژورنال: Chemical and Pharmaceutical Bulletin
سال: 2002
ISSN: 0009-2363,1347-5223
DOI: 10.1248/cpb.50.1531